TOCOBIOL® – Blend of Tocopherols

TOCOBIOL® – Blend of Tocopherols

Antioxidants of natural origin for your food products

TOCOBIOL® is a range of antioxidants of natural origin manufactured by the Spanish company BTSA and distributed by Elementa.

These tocopherol blends of natural origin are derived from non-GMO soybean oil or sunflower oil. According to Annex II of Regulation 1129/2011, soybean oils and soybean tocopherols are exempted from any allergen declaration.

TOCOBIOL® is an excellent choice to protect unsaturated oils and food products containing them, thereby extending their shelf life.

TOCOBIOL® is a wide range of non-allergenic tocopherols of natural origin designed for food and nutritional products. They effectively protect unsaturated fats in food products, preserving their active ingredients and extending their shelf life.

1. Natural and Upcycled Ingredients
2. Antioxidant Activity of TOCOBIOL®
3. What is Oxidative Rancidity?
4. How Does TOCOBIOL® Work?
5. The TOCOBIOL® Range

1. Natural and Upcycled Ingredients

TOCOBIOL® is composed of a blend of tocopherols of natural origin: α-tocopherol, β-tocopherol, γ-tocopherol, and δ-tocopherol.

These antioxidants are upcycled ingredients obtained from the valorization of co-products from the oil industry, such as non-GMO soybean and sunflower by-products. Naturally present in vegetable oils, they are extracted from the deodorization by-products of these oils.

TOCOBIOL® ingredients are kosher and halal certified.

2. Antioxidant Activity of TOCOBIOL®

Thanks to its composition, TOCOBIOL® exhibits ideal antioxidant properties for use in food products.

Contrary to common belief, D-α-tocopherol (vitamin E) is not an effective antioxidant and should not be used to protect food from oxidation. Blends of tocopherols of natural origin, especially those rich in δ-tocopherol and γ-tocopherol, are more effective for food preservation. Soy-derived tocopherols, which contain an average of 88% of these components, are particularly suitable.

TOCOBIOL® is therefore ideal for protecting fats and oils from oxidative rancidity, allowing food products to retain their organoleptic and nutritional properties over time.

3. What is Oxidative Rancidity?

Oxidative rancidity is a spontaneous oxidation process that occurs when unsaturated fatty acids (with at least one double bond) are exposed to oxygen.

Factors such as heat, light, humidity, and the presence of metals like iron, zinc, and copper can accelerate this phenomenon.

This chemical process is characterized by a chain reaction where free radicals attack fatty acids, generating more radicals in the process. This leads to the degradation of the food's organoleptic qualities (unpleasant taste, odor, etc.) and its nutritional value over time.

4. How Does TOCOBIOL® Work?

Tocopherols, thanks to their antioxidant properties, oxidize in place of unsaturated fatty acids. Unlike the latter, tocopherols stabilize into forms that do not evolve into radical states. This prevents free radicals from attacking fatty acids in foods.

TOCOBIOL®’s mechanism of action can be summarized as follows:

  • Neutralizing free radicals
  • Donating phenolic hydrogen atoms to free radicals
  • Converting free radicals into stable, non-reactive forms

The antioxidant effectiveness of TOCOBIOL® has been demonstrated through various Rancimat tests conducted by BTSA.

5. The TOCOBIOL® Range

BTSA develops tailored solutions to meet the specific needs of each client, ensuring optimal efficiency for every application type.

The range includes two categories of ingredients:

  • Tocobiol®:
    - Products containing 18% tocopherol blends
    - More concentrated products with 30% to 90% tocopherol content
  • Tocobiol® Blends:
    - A range of customized antioxidants combining Tocobiol® with other natural or synthetic ingredients to create a synergistic effect and enhance antioxidant capacity (e.g., Tocobiol® + green tea extract or Tocobiol® + ascorbyl palmitate).

Tocopherols extracted from soybean oil are non-allergenic. However, sunflower-based tocopherols are also available in the range.

No Allergen or GMO Labeling Required

Soy-based tocopherols, as well as fully refined soybean oils and fats, are exempt from allergen labeling in accordance with EU Regulation No 1169/2011 of October 25, 2011 (Annex II).

BTSA’s traceability system ensures that TOCOBIOL® products are derived from non-GMO soy. This system complies with the requirements of the IP certification system and with Regulations 1829/2003/EC and 1830/2003/EC.

Tocopherol blends, compliant with E306*, are approved for use as antioxidants in processed organic food products under the Implementing Regulation (EU) No 2016/673 regarding organic production, labeling, and controls.

Compliance with E306* is indicated in the technical data sheet for each product reference.

What is E306?
*E306 is a tocopherol-rich extract that serves as an antioxidant as defined by EU Regulation No 1333/2008. The purity criteria for E306 are specified in Regulation (EU) No 231/2012.

1. How is TOCOBIOL® Produced?

Tocopherols are obtained from by-products of the deodorization process of edible vegetable oils. These tocopherols are then concentrated through molecular distillation.

2. What Are the Benefits of the TOCOBIOL® Range for Your Food Products?

  • Protects fats in cereals, plant-based cheeses and desserts, bakery products, and more;
  • Increase products shelf life;
  • Effective at low doses, TOCOBIOL® does not alter the taste or color of the final products;
  • Remains stable at high temperatures;
  • Synergistic effect with several antioxidants when used in TOCOBIOL® blends

3. Available Forms

To adapt to all your formulations, TOCOBIOL® is available in various forms:

  • Oil-based
  • Powder
  • Oil-soluble
  • Water-dispersible
  • Applications

Suitable for a wide range of applications, including:

  • Oils and fats
  • Confectionery and bakery products
  • Snacks and cereals
  • Cocoa and chocolate
  • Spices and condiments
  • Sauces and dressings
  • Meat-based products
  • Baby food


The typical incorporation rate ranges from 0.1% to 0.3% (1,000 to 3,000 ppm) of the total formula.

Depending on the application, it can vary from 0.05% to 1% (500 to 10,000 ppm).